ID 9951
File
Authors
Domi, Yasuhiro Department of Chemistry and Biotechnology, Graduate School of Engineering and Center for Research on Green Sustainable Chemistry, Tottori University Researchers DB KAKEN
Usui, Hiroyuki Department of Chemistry and Biotechnology, Graduate School of Engineering and Center for Research on Green Sustainable Chemistry, Tottori University Researchers DB KAKEN
Sugimoto, Kai Course of Chemistry and Biotechnology, Department of Engineering, Graduate School of Sustainability Science and Center for Research on Green Sustainable Chemistry, Tottori University
Gotoh, Kazuma Graduate School of Natural Science & Technology, Okayama University, Okayama / Element Strategy Initiative for Catalysis and Batteries (ESICB), Kyoto University
Nishikawa, Kei International Center of Young Scientists, National Institute for Materials Science
Sakaguchi, Hiroki Department of Chemistry and Biotechnology, Graduate School of Engineering and Center for Research on Green Sustainable Chemistry, Tottori University Researchers DB KAKEN
Abstract
Silicides are attractive novel active materials for use in the negative-electrodes of next-generation lithium-ion batteries that use certain ionic-liquid electrolytes; however, the reaction mechanism of the above combination is yet to be clarified. Possible reactions at the silicide electrode are as follows: deposition and dissolution of Li metal on the electrode, lithiation and delithiation of Si, which would result from the phase separation of the silicide, and alloying and dealloying of the silicide with Li. Herein, we examined these possibilities using various analysis methods. The results revealed that the lithiation and delithiation of silicide occurred.
Publisher
American Chemical Society
Content Type
Journal Article
Link
ISSN
24701343
Journal Title
ACS OMEGA
Volume
5
Issue
35
Start Page
22631
End Page
22636
Published Date
2020-09-08
Publisher-DOI
Text Version
Publisher
Rights
(C) 2020 American Chemical Society. This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
Citation
Domi Yasuhiro, Usui Hiroyuki, Sugimoto Kai, et al. Reaction Behavior of a Silicide Electrode with Lithium in an Ionic-Liquid Electrolyte. ACS OMEGA. 2020. 5(35). 22631-22636. doi:10.1021/acsomega.0c03357
Department
Faculty of Engineering/Graduate School of Engineering
Language
English
Web of Science Key ut
WOS:000570009400068