| File | |
| Authors |
Isoda, Yuta
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University
Sasaki, Norihiko
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University
Kitamura, Kei
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University
Takahashi, Shuji
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University
Manmode, Sujit
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University
Takeda-Okuda, Naoko
Department of Regional Environment, Faculty of Regional Sciences, Tottori University
Tamura, Jun-ichi
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University / Department of Regional Environment, Faculty of Regional Sciences, Tottori University / Center for Research on Green Sustainable Chemistry, Faculty of Engineering, Tottori University
Researchers DB
KAKEN
Nokami, Toshiki
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University / Center for Research on Green Sustainable Chemistry, Faculty of Engineering, Tottori University
Researchers DB
KAKEN
Itoh, Toshiyuki
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University / Center for Research on Green Sustainable Chemistry, Faculty of Engineering, Tottori University
Researchers DB
KAKEN
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| Keywords | automated synthesis
electrochemical oxidation
glycosylation
glucosamine
total synthesis
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| Abstract | The total synthesis of TMG-chitotriomycin using an automated electrochemical synthesizer for the assembly of carbohydrate building blocks is demonstrated. We have successfully prepared a precursor of TMG-chitotriomycin, which is a structurally-pure tetrasaccharide with typical protecting groups, through the methodology of automated electrochemical solution-phase synthesis developed by us. The synthesis of structurally well-defined TMG-chitotriomycin has been accomplished in 10-steps from a disaccharide building block.
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| Publisher | Beilstein-Institut
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| Content Type |
Journal Article
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| Link | |
| ISSN | 18605397
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| Journal Title | BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
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| Volume | 13
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| Start Page | 919
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| End Page | 924
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| Published Date | 2017-05-16
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| Publisher-DOI | |
| Text Version |
Publisher
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| Rights | © 2017 Isoda et al.; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (http://www.beilstein-journals.org/bjoc)
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| Citation | Isoda Yuta, Sasaki Norihiko, Kitamura Kei, et al. Total synthesis of TMG-chitotriomycin based on an automated electrochemical assembly of a disaccharide building block. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY. 2017. 13. 919-924. doi:10.3762/bjoc.13.93
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| Department |
Faculty of Engineering/Graduate School of Engineering
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| Language |
English
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| Web of Science Key ut | WOS:000407582000002
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