Authors
Suganuma, Satoshi Center for Research on Green Sustainable Chemistry, Tottori University Researchers DB KAKEN
Arita, Kohsuke Center for Research on Green Sustainable Chemistry, Tottori University
Nakano, Fumiya Center for Research on Green Sustainable Chemistry, Tottori University
Tsuji, Etsushi Center for Research on Green Sustainable Chemistry, Tottori University Researchers DB KAKEN
Katada, Naonobu Center for Research on Green Sustainable Chemistry, Tottori University Researchers DB KAKEN
Keywords
Adsorption
vacuum gas oil
basic nitrogen-containing compounds
amorphous silica-alumina
kinetics
reusability
Abstract
The adsorption behavior of basic compounds in practical vacuum gas oil is quantitatively analyzed on amorphous silica-alumina with acid sites, mesopores and thermal stability. Time course of adsorption capacity was found to be controlled by kinetics but not by equilibrium. The rate of adsorption was found to have pseudo second-order but not pseudo first-order kinetics, indicating that the adsorption rate was mainly controlled by the diffusion of large molecules. The particle size did not influence the adsorption quantity at equilibrium, whereas the smaller particle size increased the adsorption rate. The adsorption quantity at equilibrium was influenced by the molecular structure of basic compound due to steric hinderance around the basic site, whereas the adsorption rate strongly depended on the molecular size, supporting that the adsorption rate was mainly controlled by the diffusion of compounds in the pores of amorphous silica-alumina. Comparison of solvents showed that the adsorption quantity at equilibrium was influenced by the polarity but not by the molecular size, while the adsorption rate strongly depended on both the polarity and molecular size. The reusability of adsorbent silica-alumina was demonstrated by the stable adsorption capacity and rate after calcination for the regeneration.
Content Type
Journal Article
Link
ISSN
00162361
NCID
AA00652288
Journal Title
Fuel
Volume
266
Start Page
117055
Published Date
2020-04-15
Publisher-DOI
Text Version
Author
Rights
© 2020 Elsevier Ltd. All rights reserved.
Citation
Suganuma, Satoshi. Arita, Kohsuke. Nakano, Fumiya. et al. Adsorption kinetics in removal of basic nitrogen-containing compounds from practical heavy oils by amorphous silica-alumina. Fuel. 266. 117055. 2020-04-15.
Department
Faculty of Engineering/Graduate School of Engineering
Language
English
pii
S0016-2361(20)30050-8