| File | |
| Authors |
Mitsuyoshi, Daisuke
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University
Kuroiwa, Koji
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University
Kataoka, Yuta
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University
Nakagawa, Takuya
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University
Kosaka, Misaki
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University
Nakamura, Koshiro
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University
Suganuma, Satoshi
Center for Researches on Green Sustainable Chemistry, Faculty of Engineering, Tottori University
Researchers DB
KAKEN
Araki, Yasuhiro
Central Technical Research Laboratory, JX Nippon Oil & Energy Corp
Katada, Naonobu
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University
Researchers DB
KAKEN
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| Keywords | Shape selectivity
Toluene disproportionation
para-Xylene
MFI zeolite
Chemical vapor deposition of silica
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| Abstract | Dependence of shape selectivity for para-xylene production by toluene disproportionation on conditions of chemical vapor deposition (CVD) of tetramethoxysilane on MFI (ZSM-5) zeolite were investigated in detail. The CVD after pelletization was necessary to obtain 0.7–1 mm particles with high selectivity. The influences of preparation conditions on the selectivity were investigated in detail to find the optimum conditions. The parent zeolite with small number of Brønsted acid sites on the external surface brought the high selectivity after the CVD. The catalyst prepared in the optimized conditions showed the selectivity 99.7% at ca. 10% of the toluene conversion.
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| Content Type |
Journal Article
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| Link | |
| ISSN | 13871811
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| NCID | AA11160707
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| Journal Title | Microporous and Mesoporous Materials
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| Volume | 242
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| Start Page | 118
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| End Page | 126
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| Published Date | 2017-04-30
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| Publisher-DOI | |
| Text Version |
Author
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| Rights | © 2017 Elsevier Inc. All rights reserved.
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| Citation | Mitsuyoshi, Daisuke. Kuroiwa, Koji. Kataoka, Yuta. et al. Shape selectivity in toluene disproportionation into para-xylene generated by chemical vapor deposition of tetramethoxysilane on MFI zeolite catalyst. Microporous and Mesoporous Materials. 242. 118-126. 2017-04-30.
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| Department |
Faculty of Engineering/Graduate School of Engineering
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| Language |
English
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| pii | S1387-1811(17)30022-7
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