| フルテキストファイル | |
| 著者 |
Suganuma Satoshi
Center for Research on Green Sustainable Chemistry, Graduate School of Engineering, Tottori University
研究者総覧
KAKEN
Zhang Haiyan
State Key Lab of Inorganic Synthesis and Preparative Chemistry, Jilin University
Yang Chengguang
State Key Lab of Inorganic Synthesis and Preparative Chemistry, Jilin University
Xiao Feng-Shou
Key Lab of Applied Chemistry of Zhejiang Province, Zhejiang University
Katada Naonobu
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University
研究者総覧
KAKEN
|
| キーワード | BEA zeolite
Acidic property
Seed-directed synthesis
OSDA-free
|
| 抄録 | The acidic property of a BEA zeolite prepared by a seed-directed synthesis (SDS) method without organic structure directing agent (OSDA) was analyzed by a method of ammonia infrared / mass spectroscopic (IRMS) temperature-programmed desorption (TPD). The number of Brønsted acid sites on the SDS-BEA zeolite was larger than that on a conventional BEA zeolite synthesized from using OSDA. The enthalpy of ammonia desorption, distributed mainly in a range between 115 and 145 kJ mol-1, was in agreement with the acid strength region generated by isomorphous substitution of Si4+ by Al3+ in the BEA framework. These observations confirm that the microstructure around the incorporated Al in the SDS-BEA zeolite was equivalent to that in the conventional one.
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| 出版者 | Springer
|
| 資料タイプ |
学術雑誌論文
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| 外部リンク | |
| ISSN | 15734854
|
| 書誌ID | AA12120978
|
| 掲載誌名 | Journal of porous materials
|
| 最新掲載誌名 |
Journal of porous materials
|
| 巻 | 23
|
| 号 | 2
|
| 開始ページ | 415
|
| 終了ページ | 421
|
| 発行日 | 2016
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| 出版者DOI | |
| 著者版フラグ |
著者版
|
| 著作権表記 | © Springer Science+Business Media New York 2015
|
| 掲載情報 | Suganuma, S., Zhang, H., Yang, C. et al. Acidic Property of BEA Zeolite Synthesized by Seed-directed Method. Journal of porous materials. 2016, 23(2), 415-421 / This is a post-peer-review, pre-copyedit version of an article published in "Journal of porous materials". The final authenticated version is available online at: http://doi.org/10.1007/s10934-015-0095-6.
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| 部局名 |
工学部・工学研究科
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| 言語 |
英語
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