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Adsorption kinetics in removal of basic nitrogen-containing compounds from practical heavy oils by amorphous silica-alumina 90731753 菅沼, 学史 スガヌマ, サトシ Suganuma, Satoshi アリタ, コウスケ ナカノ, フミヤ 80610443 辻, 悦司 ツジ, エツシ Tsuji, Etsushi 00243379 片田, 直伸 カタダ, ナオノブ Katada, Naonobu Arita, Kohsuke アリタ, コウスケ Nakano, Fumiya ナカノ, フミヤ © 2020 Elsevier Ltd. All rights reserved. Adsorption vacuum gas oil basic nitrogen-containing compounds amorphous silica-alumina kinetics reusability Adsorption vacuum gas oil basic nitrogen-containing compounds amorphous silica-alumina kinetics reusability The adsorption behavior of basic compounds in practical vacuum gas oil is quantitatively analyzed on amorphous silica-alumina with acid sites, mesopores and thermal stability. Time course of adsorption capacity was found to be controlled by kinetics but not by equilibrium. The rate of adsorption was found to have pseudo second-order but not pseudo first-order kinetics, indicating that the adsorption rate was mainly controlled by the diffusion of large molecules. The particle size did not influence the adsorption quantity at equilibrium, whereas the smaller particle size increased the adsorption rate. The adsorption quantity at equilibrium was influenced by the molecular structure of basic compound due to steric hinderance around the basic site, whereas the adsorption rate strongly depended on the molecular size, supporting that the adsorption rate was mainly controlled by the diffusion of compounds in the pores of amorphous silica-alumina. Comparison of solvents showed that the adsorption quantity at equilibrium was influenced by the polarity but not by the molecular size, while the adsorption rate strongly depended on both the polarity and molecular size. The reusability of adsorbent silica-alumina was demonstrated by the stable adsorption capacity and rate after calcination for the regeneration. 2020-04-15 eng journal article AM https://repository.lib.tottori-u.ac.jp/records/7199 10.1016/j.fuel.2020.117055 Suganuma, Satoshi. Arita, Kohsuke. Nakano, Fumiya. et al. Adsorption kinetics in removal of basic nitrogen-containing compounds from practical heavy oils by amorphous silica-alumina. Fuel. 266. 117055. 2020-04-15. https://www.sciencedirect.com/science/article/pii/S0016236120300508 https://www.sciencedirect.com/science/article/pii/S0016236120300508 AA00652288 00162361 Fuel Fuel 266 117055 https://repository.lib.tottori-u.ac.jp/record/7199/files/fu266_117055.pdf application/pdf 238.9 kB 2022-04-15