{"created":"2023-08-02T03:53:00.667851+00:00","id":1707,"links":{},"metadata":{"_buckets":{"deposit":"8088df15-d82c-4da7-8327-0c61093a4956"},"_deposit":{"created_by":10,"id":"1707","owners":[10],"pid":{"revision_id":0,"type":"depid","value":"1707"},"status":"published"},"_oai":{"id":"oai:repository.lib.tottori-u.ac.jp:00001707","sets":["1:6","2:14","23:38:72:440"]},"author_link":["31056","31057","31058","31059"],"item_3_alternative_title_31":{"attribute_name":"タイトル（ヨミ）","attribute_value_mlt":[{"subitem_alternative_title":"ホウワ　シボウサン　エステル　ノ　ネツブンカイ　（ダイⅠホウ） : カプロンサン　メチル　エチル　n-プロピルエステル　ノ　ネツブンカイ","subitem_alternative_title_language":"ja-Kana"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1964-12-15","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"108","bibliographicPageStart":"100","bibliographicVolumeNumber":"15","bibliographic_titles":[{"bibliographic_title":"鳥取大学学芸学部研究報告. 自然科学","bibliographic_titleLang":"ja"},{"bibliographic_title":"Liberal arts journal. Natural science","bibliographic_titleLang":"en"}]}]},"item_3_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"1. Caproic acid, methyl-, ethyl- and n-propyl caproate were pyrolyzed. In gaseous products of these substances were recognized hydrogen, carbon monoxide, methane, carbon dioxide, ethane, ethylene, propane, propylene, n-butane, butane-1, iso-butane, trans-butane-2, cis-butane-2, n-pentane and pentene-1. 2. Scarcely any change in acid value of the pyrolyzed liquid of methyl ester was observed with increasing temperature. The same result held good in percentage of decomposition. 3. Ethyl- and n-propyl ester showed, with increasing temperature, a remarkable increase in acid value, and, on the other hand, a decrease  in ester value. Gaschromatogram also showed the increasing tendency in caproic acid as free fatty acid. 4. In pyrolyzed gas of methyl ester were recognized carbon monoxide and methane in comparatively large amount ; of ethyl ester, much ethylene was detected ; of n-propyl ester, a large amount of propylene was observed. 5. Such ester containing beta-hydrogen as ethyl ester or n-propyl could easily be pyro-lyzed into acid and olefin, while methyl ester without beta-hydrogen could hardly be pyrolyzed into acid and olefin.","subitem_description_type":"Other"}]},"item_3_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"鳥取大学学芸学部"}]},"item_3_relation_16":{"attribute_name":"情報源","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"鳥取大学学芸学部研究報告. 自然科学. 1964, 15, 100-108"}]}]},"item_3_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"注があるものを除き、この著作物は日本国著作権法により保護されています。 / This work is protected under Japanese Copyright Law unless otherwise noted."}]},"item_3_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00174530","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"04935608","subitem_source_identifier_type":"ISSN"}]},"item_3_text_32":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"鳥取大学教育学部化学教室"}]},"item_3_text_33":{"attribute_name":"著者所属（英）","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"*"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"宮川, 正美"},{"creatorName":"ミヤガワ, マサヨシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"荒木, 次郎"},{"creatorName":"アラキ, ジロー","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Miyagawa, Masayoshi","creatorNameLang":"en"},{"creatorName":"ミヤガワ, マサヨシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"ARAKI, Jiro","creatorNameLang":"en"},{"creatorName":"アラキ, ジロー","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper"}]},"item_title":"飽和脂肪酸エステルの熱分解（第Ⅰ報） : カプロン酸メチル,エチル,n-プロピルエステルの熱分解","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"飽和脂肪酸エステルの熱分解（第Ⅰ報） : カプロン酸メチル,エチル,n-プロピルエステルの熱分解","subitem_title_language":"ja"}]},"item_type_id":"3","owner":"10","path":["6","14","440","1712112934794"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-12-26"},"publish_date":"2018-12-26","publish_status":"0","recid":"1707","relation_version_is_last":true,"title":["飽和脂肪酸エステルの熱分解（第Ⅰ報） : カプロン酸メチル,エチル,n-プロピルエステルの熱分解"],"weko_creator_id":"10","weko_shared_id":-1},"updated":"2024-04-04T00:40:26.308594+00:00"}