{"created":"2023-08-02T03:54:38.088566+00:00","id":3477,"links":{},"metadata":{"_buckets":{"deposit":"8594272a-fa10-4adb-9b4e-e1e79924458b"},"_deposit":{"created_by":10,"id":"3477","owners":[10],"pid":{"revision_id":0,"type":"depid","value":"3477"},"status":"published"},"_oai":{"id":"oai:repository.lib.tottori-u.ac.jp:00003477","sets":["1:10","2:14","23:39:708"]},"author_link":["4287","33876","33877"],"item_3_alternative_title_31":{"attribute_name":"タイトル（ヨミ）","attribute_value_mlt":[{"subitem_alternative_title":"アゾキシベンゼン　ノ　ハンノウセイ　ニカンスル　ケンキュウ　（ダイ１ポウ） : 2,2'-ジメチルアゾキシベンゼン　ノ　ワラッハ　テンイ","subitem_alternative_title_language":"ja-Kana"}]},"item_3_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1970-12-20","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"49","bibliographicPageStart":"45","bibliographicVolumeNumber":"1","bibliographic_titles":[{"bibliographic_title":"鳥取大学工学部研究報告","bibliographic_titleLang":"ja"},{"bibliographic_title":"Reports of the Faculty of Engineering, Tottori University","bibliographic_titleLang":"en"}]}]},"item_3_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"　In this paper we authors studied on Wallach rearrangement reaction of 2,2'-dimethyl azoxybenzene (DMAB) using sulfuric acid, chlorosulfonic acid and some other weak acids as catalysts, and obtained the following results ; (1) We could obtain 4-hydroxy-2,2'-dimethyl azobenzene as a rearrangement product from DMAB in 80% sulfuric acid, under the reaction temperature 80℃ and time 30 minutes. The yield of 64% obtained in this experiment was better than that of 31% at which Gore et al had obtained the product.  (2) In case where chlorosulfonic acid was used in the rearrangement, It is a contradictory results against Wallach rearrangement by ordinary acid catalysts. The yield of o-isomer in the reaction products was higher than that of p-isomer in rearrangement. (3) We also tried Wallach rearrangement by weak acids for the first taime, and obtained p-isomer at yield of max. 38.8% with trichloroacetic acid in acetic anhydride.","subitem_description_type":"Other"}]},"item_3_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"鳥取大学工学部"}]},"item_3_relation_16":{"attribute_name":"情報源","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"鳥取大学工学部研究報告. 1970, 1(1), 45-49"}]}]},"item_3_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"注があるものを除き、この著作物は日本国著作権法により保護されています。 / This work is protected under Japanese Copyright Law unless otherwise noted."}]},"item_3_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00174610","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03858596","subitem_source_identifier_type":"ISSN"}]},"item_3_text_32":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"鳥取大学工学部工業化学科"},{"subitem_text_value":"永和化成工業K.K."}]},"item_3_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"山本, 二郎"},{"creatorName":"ヤマモト, ジロウ","creatorNameLang":"ja-Kana"},{"creatorName":"Yamamoto, Jiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"4287","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"30032022","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=30032022"}]},{"creatorNames":[{"creatorName":"佐藤, 憲章"},{"creatorName":"サトウ, ノリアキ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"33876","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sato, Noriaki","creatorNameLang":"en"},{"creatorName":"サトウ, ノリアキ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"33877","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2009-12-09"}],"displaytype":"detail","filename":"rfetu1(1)_45(1).pdf","filesize":[{"value":"329.7 kB"}],"format":"application/pdf","licensefree":"注があるものを除き、この著作物は日本国著作権法により保護されています。 / This work is protected under Japanese Copyright Law unless otherwise noted.","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"rfetu1(1)_45(1).pdf","url":"https://repository.lib.tottori-u.ac.jp/record/3477/files/rfetu1(1)_45(1).pdf"},"version_id":"bf45e905-1426-488d-a59b-da9514f1838c"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"アゾキシベンゼンの反応性に関する研究（第1報） : 2,2'-ジメチルアゾキシベンゼンのワラッハ転位","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"アゾキシベンゼンの反応性に関する研究（第1報） : 2,2'-ジメチルアゾキシベンゼンのワラッハ転位","subitem_title_language":"ja"},{"subitem_title":"Reactivities of azoxybenzenes (I) : Wallach rearrangement of 2,2'-dimetlyl azoxybenzene","subitem_title_language":"en"}]},"item_type_id":"3","owner":"10","path":["14","10","708"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-06-22"},"publish_date":"2018-06-22","publish_status":"0","recid":"3477","relation_version_is_last":true,"title":["アゾキシベンゼンの反応性に関する研究（第1報） : 2,2'-ジメチルアゾキシベンゼンのワラッハ転位"],"weko_creator_id":"10","weko_shared_id":-1},"updated":"2023-09-27T02:52:23.040053+00:00"}