{"created":"2023-08-02T03:57:57.684201+00:00","id":7077,"links":{},"metadata":{"_buckets":{"deposit":"81c26bdd-f433-4738-be74-4969f565ac7a"},"_deposit":{"created_by":10,"id":"7077","owners":[10],"pid":{"revision_id":0,"type":"depid","value":"7077"},"status":"published"},"_oai":{"id":"oai:repository.lib.tottori-u.ac.jp:00007077","sets":["1:10","2:12"]},"author_link":["254","4098","3101","26168"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2021-04-06","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"13","bibliographicPageEnd":"8869","bibliographicPageStart":"8862","bibliographicVolumeNumber":"6","bibliographic_titles":[{"bibliographic_title":"ACS OMEGA"},{"bibliographic_title":"ACS OMEGA","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We have reported the effects of substituting a transition metal in silicide on the electrochemical performance of the silicide/Si composite anode for lithium-ion batteries (LIBs); the Cr0.5V0.5Si2/Si electrode exhibited much better cyclability compared with CrSi2/Si and VSi2/Si electrodes. Herein, we investigated the electrochemical performance of a CrxV1–xSi2/Si slurry electrode for its application in LIBs, and the results obtained were compared to those of a gas deposition (GD) electrode, which was comprised of only active materials. The slurry electrode exhibited a superior cycling life as with the GD electrode. After charge–discharge cycles, the expansion of the electrode thickness of CrSi2/Si and Cr0.5V0.5Si2/Si was smaller than that of VSi2/Si, and VSi2 was significantly pulverized compared with the other silicides. It is considered that VSi2 deformed easily by the stress from Si expansion and pulverized because the hardness of VSi2 was the smallest among the silicides used in this study. These results reveal that Cr0.5V0.5Si2/Si has great potential as an anode material for next-generation LIBs and hardness is an important property for compositing silicide with Si.","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society"}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1021/acsomega.0c05986","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_16":{"attribute_name":"情報源","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"Kimura Yuta, Domi Yasuhiro, Usui Hiroyuki, et al. Anode Properties of CrxV1-xSi2/Si Composite Electrodes for LithiumIon Batteries. ACS OMEGA. 2021. 6(13). 8862-8869. doi:10.1021/acsomega.0c05986"}]}]},"item_10001_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://pubs.acs.org/doi/10.1021/acsomega.0c05986"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://pubs.acs.org/doi/10.1021/acsomega.0c05986","subitem_relation_type_select":"URI"}}]},"item_10001_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"(C) 2021 The Authors. Published by American Chemical Society"}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"24701343","subitem_source_identifier_type":"ISSN"}]},"item_10001_text_33":{"attribute_name":"著者所属（英）","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering and Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_language":"en","subitem_text_value":" Department of Chemistry and Biotechnology, Graduate School of Engineering and Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_language":"en","subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering and Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_language":"en","subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering and Center for Research on Green Sustainable Chemistry, Tottori University"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"道見, 康弘"},{"creatorName":"ドウミ, ヤスヒロ","creatorNameLang":"ja-Kana"},{"creatorName":"Domi, Yasuhiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"254","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"50576717","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=50576717"},{"nameIdentifier":"100001303","nameIdentifierScheme":"研究者総覧鳥取大学","nameIdentifierURI":"http://researchers.adm.tottori-u.ac.jp/html/100001303_ja.html"}]},{"creatorNames":[{"creatorName":"薄井, 洋行"},{"creatorName":"ウスイ, ヒロユキ","creatorNameLang":"ja-Kana"},{"creatorName":"Usui, Hiroyuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"4098","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"60423240","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=60423240"},{"nameIdentifier":"100000473","nameIdentifierScheme":"研究者総覧鳥取大学","nameIdentifierURI":"http://researchers.adm.tottori-u.ac.jp/html/100000473_ja.html"}]},{"creatorNames":[{"creatorName":"坂口, 裕樹"},{"creatorName":"サカグチ, ヒロキ","creatorNameLang":"ja-Kana"},{"creatorName":"Sakaguchi, Hiroki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"3101","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"00202086","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=00202086"},{"nameIdentifier":"100000517","nameIdentifierScheme":"研究者総覧鳥取大学","nameIdentifierURI":"http://researchers.adm.tottori-u.ac.jp/html/100000517_ja.html"}]},{"creatorNames":[{"creatorName":"Kimura, Yuta","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"26168","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-03-17"}],"displaytype":"detail","filename":"acso6(13)_8862.pdf","filesize":[{"value":"14.6 MB"}],"format":"application/pdf","licensefree":"(C) 2021 The Authors. 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