{"created":"2023-08-02T03:58:00.661498+00:00","id":7130,"links":{},"metadata":{"_buckets":{"deposit":"296b9b13-e8e0-41ae-965c-fafc61673450"},"_deposit":{"created_by":10,"id":"7130","owners":[10],"pid":{"revision_id":0,"type":"depid","value":"7130"},"status":"published"},"_oai":{"id":"oai:repository.lib.tottori-u.ac.jp:00007130","sets":["1:10","2:12"]},"author_link":["26403","26404","4778","4855","1334","26405","26406"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-12-31","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"107","bibliographicPageStart":"103","bibliographicVolumeNumber":"102","bibliographic_titles":[{"bibliographic_title":"Catalysis Communications"},{"bibliographic_title":"Catalysis Communications","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Reaction rates of toluene disproportionation (A) and cumene cracking (B) normalized by the number of Brønsted acid sites were analyzed on aluminosilicates. The activation entropy showed linear and compensatory relationship against the activation enthalpy. The slope of entropy-enthalpy plot was in the order of (B)>(A)>small alkane cracking, whereas the intercept on the horizontal axis was in the order of propane and isobutane cracking>linear C4–8 alkanes and iso-pentane cracking>(A)>(B). The former is consistent with the bulkiness of reactant, while the latter is consistent with intrinsic difficulty of formation of intermediate cations.","subitem_description_type":"Other"}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.catcom.2017.08.033","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_16":{"attribute_name":"情報源","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"Nakamura, Koshiro. Mizuta, Ryo. Suganuma, Satoshi. et al. Compensation between activation entropy and enthalpy in reactions of aromatic hydrocarbons catalyzed by solid acids. Catalysis Communications. 102. 103-107. 2017-12-31."}]}]},"item_10001_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://www.sciencedirect.com/science/article/pii/S1566736717303734"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.sciencedirect.com/science/article/pii/S1566736717303734","subitem_relation_type_select":"URI"}}]},"item_10001_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2017 Elsevier B.V. All rights reserved."}]},"item_10001_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA1180723X","subitem_source_identifier_type":"NCID"}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"15667367","subitem_source_identifier_type":"ISSN"}]},"item_10001_text_33":{"attribute_name":"著者所属（英）","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University"},{"subitem_text_language":"en","subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University"},{"subitem_text_language":"en","subitem_text_value":"Center for Research on Green Sustainable Chemistry, Faculty of Engineering, Tottori University"},{"subitem_text_language":"en","subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University"},{"subitem_text_language":"en","subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"ナカムラ, コウシロウ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"ミズタ, リョウ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"菅沼, 学史"},{"creatorName":"スガヌマ, サトシ","creatorNameLang":"ja-Kana"},{"creatorName":"Suganuma, Satoshi","creatorNameLang":"en"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"辻, 悦司"},{"creatorName":"ツジ, エツシ","creatorNameLang":"ja-Kana"},{"creatorName":"Tsuji, Etsushi","creatorNameLang":"en"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"片田, 直伸"},{"creatorName":"カタダ, ナオノブ","creatorNameLang":"ja-Kana"},{"creatorName":"Katada, Naonobu","creatorNameLang":"en"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Nakamura, Koshiro","creatorNameLang":"en"},{"creatorName":"ナカムラ, コウシロウ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Mizuta, Ryo","creatorNameLang":"en"},{"creatorName":"ミズタ, リョウ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-03-17"}],"displaytype":"detail","filename":"cc102_103.pdf","filesize":[{"value":"447.5 kB"}],"format":"application/pdf","licensefree":"© 2017 Elsevier B.V. All rights reserved.","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"cc102_103.pdf","url":"https://repository.lib.tottori-u.ac.jp/record/7130/files/cc102_103.pdf"},"version_id":"44b98c48-1fad-48ff-becb-0ec9ee97c425"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article"}]},"item_title":"Compensation between activation entropy and enthalpy in reactions of aromatic hydrocarbons catalyzed by solid acids","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Compensation between activation entropy and enthalpy in reactions of aromatic hydrocarbons catalyzed by solid acids","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"10","path":["12","10"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-07-29"},"publish_date":"2020-07-29","publish_status":"0","recid":"7130","relation_version_is_last":true,"title":["Compensation between activation entropy and enthalpy in reactions of aromatic hydrocarbons catalyzed by solid acids"],"weko_creator_id":"10","weko_shared_id":-1},"updated":"2023-11-22T01:46:10.180482+00:00"}