{"created":"2023-08-02T03:58:00.832003+00:00","id":7134,"links":{},"metadata":{"_buckets":{"deposit":"f3e4533c-86eb-4736-a9b3-62c8d982e177"},"_deposit":{"created_by":10,"id":"7134","owners":[10],"pid":{"revision_id":0,"type":"depid","value":"7134"},"status":"published"},"_oai":{"id":"oai:repository.lib.tottori-u.ac.jp:00007134","sets":["1:10","2:12"]},"author_link":["254","4098","26419","3101"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-10-12","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"589","bibliographicPageStart":"581","bibliographicVolumeNumber":"6","bibliographic_titles":[{"bibliographic_title":"ChemElectroChem"},{"bibliographic_title":"ChemElectroChem","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We investigated the lithiation and delithiation properties of pure binary silicide electrodes in an ionic liquid electrolyte as novel anodes for lithium‐ion batteries. Some electrodes maintain a high reversible capacity in the electrolyte, whereas they show a poor cycling performance in an organic electrolyte. The superior performance results from the high affinity for the transition metal that composes the silicide with Li. Based on reaction behavior analysis, the crystal structure of silicide is maintained during the cycling, and phase separation does not occur. The ionic liquid electrolyte suppresses the formation of cracks and exfoliation of the silicide layer from a substrate. In addition, a surface film formed on the silicide electrode through the reductive decomposition of the electrolyte has different components than that on a Si electrode, even in the same ionic liquid electrolyte. Soft X‐ray emission spectroscopy demonstrates that the pure silicide itself reacts with Li. The obtained results will provide significant insights into novel alloy‐based anode materials for lithium‐ion batteries.","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley-VCH Verlag GmbH & Co. KGaA."}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1002/celc.201801088","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_16":{"attribute_name":"情報源","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"This research was published by Wiley: DOMI, Yasuhiro, et al. Lithiation and Delithiation Reactions of Binary Silicide Electrodes in an Ionic Liquid Electrolyte as Novel Anodes for Lithium‐Ion Batteries. ChemElectroChem, 2019, 6.2: 581-589. https://doi.org"}]}]},"item_10001_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://onlinelibrary.wiley.com/doi/full/10.1002/celc.201801088"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://onlinelibrary.wiley.com/doi/full/10.1002/celc.201801088","subitem_relation_type_select":"URI"}}]},"item_10001_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2018 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is pr"}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"21960216","subitem_source_identifier_type":"ISSN"}]},"item_10001_text_33":{"attribute_name":"著者所属（英）","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Enginnering, Tottori University / Center for Research on Green Sustainable Chemistry, Tottori University / Global Research Center for Environment and Energy based on Nanomaterials Science, National Institute for Materials Science"},{"subitem_text_language":"en","subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Enginnering, Tottori University / Center for Research on Green Sustainable Chemistry, Tottori University / Global Research Center for Environment and Energy based on Nanomaterials Science, National Institute for Materials Science"},{"subitem_text_language":"en","subitem_text_value":"Graduate School of Sustainability Science, Tottori University / Center for Research on Green Sustainable Chemistry, Tottori University / Global Research Center for Environment and Energy based on Nanomaterials Science, National Institute for Materials Science"},{"subitem_text_language":"en","subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Enginnering, Tottori University / Center for Research on Green Sustainable Chemistry, Tottori University / Global Research Center for Environment and Energy based on Nanomaterials Science, National Institute for Materials Science"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Domi, Yasuhiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"254","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"50576717","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=50576717"},{"nameIdentifier":"100001303","nameIdentifierScheme":"研究者総覧鳥取大学","nameIdentifierURI":"http://researchers.adm.tottori-u.ac.jp/html/100001303_ja.html"}]},{"creatorNames":[{"creatorName":"Usui, Hiroyuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"4098","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"60423240","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=60423240"},{"nameIdentifier":"100000473","nameIdentifierScheme":"研究者総覧鳥取大学","nameIdentifierURI":"http://researchers.adm.tottori-u.ac.jp/html/100000473_ja.html"}]},{"creatorNames":[{"creatorName":"Takaishi, Rena","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"26419","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sakaguchi, Hiroki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"3101","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"00202086","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=00202086"},{"nameIdentifier":"100000517","nameIdentifierScheme":"研究者総覧鳥取大学","nameIdentifierURI":"http://researchers.adm.tottori-u.ac.jp/html/100000517_ja.html"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-03-17"}],"displaytype":"detail","filename":"cec6(2)_581.pdf","filesize":[{"value":"4.0 MB"}],"format":"application/pdf","licensefree":"© 2018 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is pr","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"cec6(2)_581.pdf","url":"https://repository.lib.tottori-u.ac.jp/record/7134/files/cec6(2)_581.pdf"},"version_id":"b319a392-9b96-4561-9d32-0d74ad39d60d"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"lithium-ion batteries","subitem_subject_scheme":"Other"},{"subitem_subject":"silicide","subitem_subject_scheme":"Other"},{"subitem_subject":"ionic liquid electrolyte","subitem_subject_scheme":"Other"},{"subitem_subject":"gas deposition","subitem_subject_scheme":"Other"},{"subitem_subject":"soft X-ray emission spectroscopy","subitem_subject_scheme":"Other"},{"subitem_subject":"lithium-ion batteries","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"silicide","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"ionic liquid electrolyte","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"gas deposition","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"soft X-ray emission spectroscopy","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Lithiation and Delithiation Reactions of Binary Silicide Electrodes in an Ionic Liquid Electrolyte as Novel Anodes for Lithium‐Ion Batteries","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Lithiation and Delithiation Reactions of Binary Silicide Electrodes in an Ionic Liquid Electrolyte as Novel Anodes for Lithium‐Ion Batteries","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"10","path":["12","10"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2019-07-09"},"publish_date":"2019-07-09","publish_status":"0","recid":"7134","relation_version_is_last":true,"title":["Lithiation and Delithiation Reactions of Binary Silicide Electrodes in an Ionic Liquid Electrolyte as Novel Anodes for Lithium‐Ion Batteries"],"weko_creator_id":"10","weko_shared_id":-1},"updated":"2023-09-29T00:35:18.813145+00:00"}