@article{oai:repository.lib.tottori-u.ac.jp:00007170, author = {Usui, Hiroyuki and Usui, Hiroyuki and Nishinami, Hiroyuki and Iida, Takahisa and Sakaguchi, Hiroki and Sakaguchi, Hiroki and Nishinami, Hiroyuki and Iida, Takahisa}, issue = {5}, journal = {Electrochemistry, Electrochemistry}, month = {Jan}, note = {Thick film electrodes of Cu-coated Si particles were fabricated by an electroless deposition and a successive gas-deposition, and were evaluated their electrochemical properties as an anode of Li-ion battery. The discharge capacity and its retention at the 1000th cycle were 570 mAh g-1 and 61%. The excellent cycle life performance is attributed to an enhanced electrical conductivity due to the Cu-coating and a reversible conversion reaction between Li and Cu2O which was formed on the Cu surface. The high capacity retention is caused by a high fracture toughness of the coated Cu which can effectively relax a stress induced by volume expansion of Si as a buffer matrix.}, pages = {329--331}, title = {Anode Properties of Cu-Coated Si Thick Film Electrodes Prepared by Electroless Deposition and Gas-Deposition}, volume = {78}, year = {2010} }