{"created":"2023-08-02T03:58:02.869697+00:00","id":7176,"links":{},"metadata":{"_buckets":{"deposit":"58596227-ff69-4887-9e14-c61b26be11a0"},"_deposit":{"created_by":10,"id":"7176","owners":[10],"pid":{"revision_id":0,"type":"depid","value":"7176"},"status":"published"},"_oai":{"id":"oai:repository.lib.tottori-u.ac.jp:00007176","sets":["1:10","2:12"]},"author_link":["4098","26560","26561","3101","26562","26563"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013-11-30","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"580","bibliographicPageStart":"575","bibliographicVolumeNumber":"111","bibliographic_titles":[{"bibliographic_title":"Electrochimica acta"},{"bibliographic_title":"Electrochimica acta","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Composites of rutile-type TiO2 and Si were synthesized by a facile sol-gel method for a high-performance anode of Li-ion battery. We have investigated anode performance of binder-free thick-film electrodes prepared by a gas-deposition method using the TiO2/Si composites obtained. The composite electrode exhibited a remarkably improved cyclability and a good high-rate performance: a discharge capacity at the 900th cycle was 710 mA h g–1, and a specific capacity per Si weight was as large as 1870 mA h g(Si)–1 even at a high current rate of 4.8C. It is suggested that a fast Li-ion diffusion in TiO2 provides smooth insertion/extraction of Li-ion into/from the composite electrodes. The results offer a utility of rutile TiO2 as a Li-ion conductor in Si-based electrodes for the next-generation Li-ion battery.","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier"}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.electacta.2013.08.015","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_16":{"attribute_name":"情報源","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"Electrochimica acta. 2013, 111, 575-580"}]}]},"item_10001_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://www.sciencedirect.com/science/article/pii/S0013468613015284"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.sciencedirect.com/science/article/pii/S0013468613015284","subitem_relation_type_select":"URI"}}]},"item_10001_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © 2013 Elsevier B.V. All rights reserved. This manuscript version is made available under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/"}]},"item_10001_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11525861","subitem_source_identifier_type":"NCID"}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00134686","subitem_source_identifier_type":"ISSN"}]},"item_10001_text_32":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Usui, Hiroyuki"},{"creatorName":"Usui, Hiroyuki","creatorNameLang":"en"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Wasada, Kuniaki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Shimizu, Masahiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sakaguchi, Hiroki"},{"creatorName":"Sakaguchi, Hiroki","creatorNameLang":"en"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Wasada, Kuniaki","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Shimizu, Masahiro","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-12-10"}],"displaytype":"detail","filename":"ea111_575.pdf","filesize":[{"value":"724.9 kB"}],"format":"application/pdf","licensefree":"Copyright © 2013 Elsevier B.V. All rights reserved. This manuscript version is made available under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ea111_575.pdf","url":"https://repository.lib.tottori-u.ac.jp/record/7176/files/ea111_575.pdf"},"version_id":"3886ee5a-8022-4915-8a1d-189d897261b3"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"TiO2/Si composite","subitem_subject_scheme":"Other"},{"subitem_subject":"Li-ion battery anode","subitem_subject_scheme":"Other"},{"subitem_subject":"Sol-gel method","subitem_subject_scheme":"Other"},{"subitem_subject":"Gas-deposition","subitem_subject_scheme":"Other"},{"subitem_subject":"Li-ion diffusion","subitem_subject_scheme":"Other"},{"subitem_subject":"TiO2/Si composite","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Li-ion battery anode","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Sol-gel method","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Gas-deposition","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Li-ion diffusion","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article"}]},"item_title":"TiO2/Si composites synthesized by sol-gel method and their improved electrode performance as Li-ion battery anodes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"TiO2/Si composites synthesized by sol-gel method and their improved electrode performance as Li-ion battery anodes","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"10","path":["12","10"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-06-22"},"publish_date":"2018-06-22","publish_status":"0","recid":"7176","relation_version_is_last":true,"title":["TiO2/Si composites synthesized by sol-gel method and their improved electrode performance as Li-ion battery anodes"],"weko_creator_id":"10","weko_shared_id":-1},"updated":"2023-09-29T00:37:36.125552+00:00"}