{"created":"2023-08-02T03:58:04.865701+00:00","id":7220,"links":{},"metadata":{"_buckets":{"deposit":"15e2d69b-06a0-4e2e-8307-ba6bbbf626cc"},"_deposit":{"created_by":10,"id":"7220","owners":[10],"pid":{"revision_id":0,"type":"depid","value":"7220"},"status":"published"},"_oai":{"id":"oai:repository.lib.tottori-u.ac.jp:00007220","sets":["1:10","2:12"]},"author_link":["26755","4098","26756","26757","2693","1108","3101","26758","26759","26760"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-11-04","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"12","bibliographicPageEnd":"10144","bibliographicPageStart":"10132","bibliographicVolumeNumber":"10","bibliographic_titles":[{"bibliographic_title":"International Journal of Electrochemical Science"},{"bibliographic_title":"International Journal of Electrochemical Science","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The electrochemical Na-insertion/extraction properties of phosphorus as a Na-ion battery anode in ionic liquid electrolytes were investigated by using a thick film without any binder or conductive additive. The ionic liquid with more electrochemically-stable cation structure, 1-((2-methoxyethoxy)methyl)-1-methylpyrrolidinium bis(fluorosulfonyl)amide (Py1MEM-FSA), delivered a high reversible capacity of 310 mA h g−1 at the 100th cycle, whereas the phosphorus electrode in 1-ethyl-3-methylimidazolium bis(fluorosulfonyl)amide (EMI-FSA) showed a low capacity of only 110 mA h g−1. It was revealed that disintegration of the electrode after cycling was effectively suppressed by applying Py1MEM-FSA instead of an organic electrolyte including propylene carbonate (PC), and that a surface layer induced by the decomposition of EMI-FSA hindered Na-insertion into the active material layer. The performance obtained in Py1MEM-FSA was very superior to that in PC. We applied for the first time a closed-system fire-resistance test to the ionic liquid electrolyte for quantitatively evaluating its non-flammability. The Py1MEM-FSA-based electrolyte exhibited an excellent fire resistance in comparison with the PC-based organic electrolyte, which can be an advantage for realizing a Na-ion battery with a high-energy density and a high safety.","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ESG"}]},"item_10001_relation_16":{"attribute_name":"情報源","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"International Journal of Electrochemical Science. 2015, 10(12), 10132-10144"}]}]},"item_10001_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://www.electrochemsci.org/papers/vol10/101210132.pdf"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.electrochemsci.org/papers/vol10/101210132.pdf","subitem_relation_type_select":"URI"}}]},"item_10001_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2015 The Authors. Published by ESG (www.electrochemsci.org). This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/4.0/)."}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"14523981","subitem_source_identifier_type":"ISSN"}]},"item_10001_text_32":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Shimizu, Masahiro"}],"nameIdentifiers":[{"nameIdentifier":"26755","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Usui, Hiroyuki"},{"creatorName":"Usui, Hiroyuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"4098","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"60423240","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=60423240"},{"nameIdentifier":"100000473","nameIdentifierScheme":"研究者総覧鳥取大学","nameIdentifierURI":"http://researchers.adm.tottori-u.ac.jp/html/100000473_ja.html"}]},{"creatorNames":[{"creatorName":"Yamane, 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Toshiyuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"1108","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"50193503","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=50193503"},{"nameIdentifier":"100000464","nameIdentifierScheme":"研究者総覧鳥取大学","nameIdentifierURI":"http://researchers.adm.tottori-u.ac.jp/html/100000464_ja.html"}]},{"creatorNames":[{"creatorName":"Sakaguchi, Hiroki"},{"creatorName":"Sakaguchi, Hiroki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"3101","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"00202086","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=00202086"},{"nameIdentifier":"100000517","nameIdentifierScheme":"研究者総覧鳥取大学","nameIdentifierURI":"http://researchers.adm.tottori-u.ac.jp/html/100000517_ja.html"}]},{"creatorNames":[{"creatorName":"Shimizu, 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Published by ESG (www.electrochemsci.org). This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/4.0/).","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ijes10(12)_10132.pdf","url":"https://repository.lib.tottori-u.ac.jp/record/7220/files/ijes10(12)_10132.pdf"},"version_id":"6082a306-22c8-4cce-8eb2-515e126bd2cb"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Electrochemical Na-Insertion/Extraction Properties of Phosphorus Electrodes in Ionic Liquid Electrolytes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Electrochemical Na-Insertion/Extraction Properties of Phosphorus Electrodes in Ionic Liquid Electrolytes","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"10","path":["12","10"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-06-22"},"publish_date":"2018-06-22","publish_status":"0","recid":"7220","relation_version_is_last":true,"title":["Electrochemical Na-Insertion/Extraction Properties of Phosphorus Electrodes in Ionic Liquid Electrolytes"],"weko_creator_id":"10","weko_shared_id":-1},"updated":"2023-09-29T00:39:56.663591+00:00"}