{"created":"2023-08-02T03:58:07.884594+00:00","id":7282,"links":{},"metadata":{"_buckets":{"deposit":"5ba09c1e-3e46-4523-a252-65bc034d4a8f"},"_deposit":{"created_by":10,"id":"7282","owners":[10],"pid":{"revision_id":0,"type":"depid","value":"7282"},"status":"published"},"_oai":{"id":"oai:repository.lib.tottori-u.ac.jp:00007282","sets":["1:10","2:12"]},"author_link":["27032","254","4098","27033","27034","2693","1108","3101","27035","27036","27037"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-01-15","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"107","bibliographicPageStart":"103","bibliographicVolumeNumber":"338","bibliographic_titles":[{"bibliographic_title":"Journal of Power Sources"},{"bibliographic_title":"Journal of Power Sources","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We investigated the influence of the anions in ionic liquid electrolytes on the electrochemical performance of a silicon (Si) negative electrode for a lithium-ion battery. While the electrode exhibited poor cycle stability in tetrafluoroborate-based and propylene carbonate-based electrolytes, better cycle performance was achieved in bis(fluorosulfonyl)amide (FSA–)- and bis(trifluoromethanesulfonyl)amide (TFSA–)-based electrolytes, in which the discharge capacity of a Si electrode was more than 1000 mA h g–1 at the 100th cycle. It is considered that a surface film derived from FSA–- and TFSA–-based electrolytes effectively suppressed continuous decomposition of the electrolyte. In a capacity limitation test, a discharge capacity of 1000 mA h g–1 was maintained even after about the 1600th cycle in the FSA–-based electrolyte, which corresponds to a cycle life almost twice as long as that in TFSA–-based electrolyte. This result should be explained by the high structural stability of FSA–-derived surface film. In addition, better rate capability with a discharge capacity of 700 mA h g–1 was obtained at a high current rate of 6 C (21 A g–1) in FSA–-based electrolyte, which was 7-fold higher than that in TFSA–-based electrolyte. These results clarified that FSA–-based ionic liquid electrolyte is the most promising candidate for Si-based negative electrodes.","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier"}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.jpowsour.2016.10.111","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_16":{"attribute_name":"情報源","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"This research was published by Elsevier Inc.: K. Yamaguchi, et al. Influence of the structure of the anion in an ionic liquid electrolyte on the electrochemical performance of a silicon negative electrode for a lithium-ion battery. Journal of Power Source"}]}]},"item_10001_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://www.sciencedirect.com/science/article/pii/S0378775316315208"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.sciencedirect.com/science/article/pii/S0378775316315208","subitem_relation_type_select":"URI"}}]},"item_10001_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © 2017 Elsevier B.V. All rights reserved. This manuscript version is made available under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/"}]},"item_10001_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00705373","subitem_source_identifier_type":"NCID"}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03787753","subitem_source_identifier_type":"ISSN"}]},"item_10001_text_32":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yamaguchi, Kazuki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Domi, Yasuhiro"},{"creatorName":"Domi, Yasuhiro","creatorNameLang":"en"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Usui, Hiroyuki"},{"creatorName":"Usui, Hiroyuki","creatorNameLang":"en"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Shimizu, Masahiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Matsumoto, Kuninobu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nokami, Toshiki"},{"creatorName":"Nokami, Toshiki","creatorNameLang":"en"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Itoh, Toshiyuki"},{"creatorName":"Itoh, Toshiyuki","creatorNameLang":"en"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Sakaguchi, Hiroki"},{"creatorName":"Sakaguchi, Hiroki","creatorNameLang":"en"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Yamaguchi, Kazuki","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Shimizu, Masahiro","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Matsumoto, Kuninobu","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-01-16"}],"displaytype":"detail","filename":"jps338_103.pdf","filesize":[{"value":"403.0 kB"}],"format":"application/pdf","licensefree":"Copyright © 2017 Elsevier B.V. All rights reserved. This manuscript version is made available under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"jps338_103.pdf","url":"https://repository.lib.tottori-u.ac.jp/record/7282/files/jps338_103.pdf"},"version_id":"21ffd2b1-c12b-45cf-b3aa-b49afc23f0b6"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Silicon","subitem_subject_scheme":"Other"},{"subitem_subject":"Li-ion battery","subitem_subject_scheme":"Other"},{"subitem_subject":"Ionic liquid electrolyte","subitem_subject_scheme":"Other"},{"subitem_subject":"Anion","subitem_subject_scheme":"Other"},{"subitem_subject":"Gas-deposition","subitem_subject_scheme":"Other"},{"subitem_subject":"Silicon","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Li-ion battery","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Ionic liquid electrolyte","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Anion","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Gas-deposition","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article"}]},"item_title":"Influence of the structure of the anion in an ionic liquid electrolyte on the electrochemical performance of a silicon negative electrode for a lithium-ion battery","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Influence of the structure of the anion in an ionic liquid electrolyte on the electrochemical performance of a silicon negative electrode for a lithium-ion battery","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"10","path":["12","10"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2019-02-04"},"publish_date":"2019-02-04","publish_status":"0","recid":"7282","relation_version_is_last":true,"title":["Influence of the structure of the anion in an ionic liquid electrolyte on the electrochemical performance of a silicon negative electrode for a lithium-ion battery"],"weko_creator_id":"10","weko_shared_id":-1},"updated":"2023-11-22T01:49:51.315748+00:00"}