{"created":"2023-08-02T03:58:08.014427+00:00","id":7284,"links":{},"metadata":{"_buckets":{"deposit":"8a3c3278-1223-420e-9e56-83e7137d2e2b"},"_deposit":{"created_by":10,"id":"7284","owners":[10],"pid":{"revision_id":0,"type":"depid","value":"7284"},"status":"published"},"_oai":{"id":"oai:repository.lib.tottori-u.ac.jp:00007284","sets":["1:10","2:12"]},"author_link":["27038","4098","27039","2693","1108","3101","27040","27041"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2014-08-08","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"12","bibliographicPageEnd":"A1771","bibliographicPageStart":"A1765","bibliographicVolumeNumber":"161","bibliographic_titles":[{"bibliographic_title":"Journal of the Electrochemical Society"},{"bibliographic_title":"Journal of the Electrochemical Society","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Ionic liquids consisted of 1-((2-methoxyethoxy)methyl)-1-methylpiperidinium (PP1MEM) or 1-hexyl-1-methylpiperidinium (PP16) and bis(trifluoromethanesulfonyl)amide (TFSA) were applied to an electrolyte for Li-ion battery. The effect of their cation structure on anode properties of Si electrodes were investigated through the use of thick film prepared by gas-deposition without any binder and conductive additive. The Si electrode in PP1MEM-TFSA exhibited an initial reversible capacity of 2670 mA h g−1, which is larger than that in PP16-TFSA by ca. 900 mA h g−1. Moreover, a comparatively high capacity of 1150 mA h g−1 at a high current density of 4200 mA g−1 is achieved in PP1MEM-TFSA whereas the Si electrode in PP16-TFSA showed the capacity of only 210 mA h g−1. Raman analysis and electrochemical impedance measurements revealed that PP1MEM cation played a role reducing the interaction between Li ion and TFSA anions, and that Li-ion transfer at the electrode−electrolyte interface in PP1MEM-TFSA was remarkably improved compared with PP16-TFSA. These results indicate that the excellent performances obtained in PP1MEM-TFSA originate from a smooth Li-insertion into Si electrode. It was suggested that introduction of ether functional group into cation is valid to enhance the electrode performance.","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The Electrochemical Society"}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1149/2.0021412jes","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_16":{"attribute_name":"情報源","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"Journal of the Electrochemical Society. 2014, 161(12), A1765-A1771"}]}]},"item_10001_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://jes.ecsdl.org/content/161/12/A1765"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://jes.ecsdl.org/content/161/12/A1765","subitem_relation_type_select":"URI"}}]},"item_10001_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2014 The Electrochemical Society. [DOI: 10.1149/2.0021412jes] All rights reserved."}]},"item_10001_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00697016","subitem_source_identifier_type":"NCID"}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00134651","subitem_source_identifier_type":"ISSN"}]},"item_10001_text_32":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Shimizu, Masahiro"}],"nameIdentifiers":[{"nameIdentifier":"27038","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Usui, Hiroyuki"},{"creatorName":"Usui, Hiroyuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"4098","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"60423240","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=60423240"},{"nameIdentifier":"100000473","nameIdentifierScheme":"研究者総覧鳥取大学","nameIdentifierURI":"http://researchers.adm.tottori-u.ac.jp/html/100000473_ja.html"}]},{"creatorNames":[{"creatorName":"Matsumoto, Kuninobu"}],"nameIdentifiers":[{"nameIdentifier":"27039","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nokami, Toshiki"},{"creatorName":"Nokami, Toshiki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"2693","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"60402963","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=60402963"},{"nameIdentifier":"100000941","nameIdentifierScheme":"研究者総覧鳥取大学","nameIdentifierURI":"http://researchers.adm.tottori-u.ac.jp/html/100000941_ja.html"}]},{"creatorNames":[{"creatorName":"Itoh, Toshiyuki"},{"creatorName":"Itoh, Toshiyuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"1108","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"50193503","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=50193503"},{"nameIdentifier":"100000464","nameIdentifierScheme":"研究者総覧鳥取大学","nameIdentifierURI":"http://researchers.adm.tottori-u.ac.jp/html/100000464_ja.html"}]},{"creatorNames":[{"creatorName":"Sakaguchi, Hiroki"},{"creatorName":"Sakaguchi, Hiroki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"3101","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"00202086","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=00202086"},{"nameIdentifier":"100000517","nameIdentifierScheme":"研究者総覧鳥取大学","nameIdentifierURI":"http://researchers.adm.tottori-u.ac.jp/html/100000517_ja.html"}]},{"creatorNames":[{"creatorName":"Shimizu, Masahiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"27040","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Matsumoto, Kuninobu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"27041","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-11-24"}],"displaytype":"detail","filename":"jes161(12)_A1765.pdf","filesize":[{"value":"2.0 MB"}],"format":"application/pdf","licensefree":"© 2014 The Electrochemical Society. [DOI: 10.1149/2.0021412jes] All rights reserved.","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"jes161(12)_A1765.pdf","url":"https://repository.lib.tottori-u.ac.jp/record/7284/files/jes161(12)_A1765.pdf"},"version_id":"c961ff09-3434-4f7f-90bd-88c663a7070e"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Effect of Cation Structure of Ionic Liquids on Anode Properties of Si Electrodes for LIB","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Effect of Cation Structure of Ionic Liquids on Anode Properties of Si Electrodes for LIB","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"10","path":["12","10"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-06-22"},"publish_date":"2018-06-22","publish_status":"0","recid":"7284","relation_version_is_last":true,"title":["Effect of Cation Structure of Ionic Liquids on Anode Properties of Si Electrodes for LIB"],"weko_creator_id":"10","weko_shared_id":-1},"updated":"2023-09-29T00:43:46.513733+00:00"}