{"created":"2023-08-02T03:58:08.804551+00:00","id":7296,"links":{},"metadata":{"_buckets":{"deposit":"b1a5a138-db58-4220-9e8f-922a5736de73"},"_deposit":{"created_by":10,"id":"7296","owners":[10],"pid":{"revision_id":0,"type":"depid","value":"7296"},"status":"published"},"_oai":{"id":"oai:repository.lib.tottori-u.ac.jp:00007296","sets":["1:10","2:12"]},"author_link":["4098","27077","27078","27079","27080","3101","27081","27082","27083","27084"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2014-09-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"64","bibliographicPageStart":"61","bibliographicVolumeNumber":"130","bibliographic_titles":[{"bibliographic_title":"Materials letters"},{"bibliographic_title":"Materials letters","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Novel composite materials consisted of elemental Si and rare-earth metal silicides, Sm–Si, Gd–Si, and Dy–Si, were synthesized and were evaluated for the first time as a high-performance anode material of Li-ion battery. Thick-film electrodes of the silicide/Si composites were prepared by an arc melting method and a successive gas-deposition method. Among them, the Gd–Si/Si composite electrode exhibited reversible Li-insertion/extraction reactions and the best cycling performance: the initial Coulombic efficiency was 80% and the discharge capacity at the 1000th cycle was 840 mA h g–1. In addition to this, the composite electrode delivered a superb high-rate performance with the capacity of 2100 mA h g–1 even at the high current rate of 12.0 A g–1 (4.8C). The remarkable performances demonstrated that the gadolinium silicide is favorable to significantly enhance anode properties of Si-based composite electrodes.","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier"}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.matlet.2014.05.065","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_16":{"attribute_name":"情報源","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"Materials letters. 2014, 130, 61-64"}]}]},"item_10001_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://www.sciencedirect.com/science/article/pii/S0167577X14008453"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.sciencedirect.com/science/article/pii/S0167577X14008453","subitem_relation_type_select":"URI"}}]},"item_10001_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © 2014 Elsevier B.V. All rights reserved. This manuscript version is made available under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/"}]},"item_10001_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11537623","subitem_source_identifier_type":"NCID"}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0167577X","subitem_source_identifier_type":"ISSN"}]},"item_10001_text_32":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"},{"subitem_text_value":"Intelligent Chemical Group, R&D Division, Santoku Corp."},{"subitem_text_value":"Intelligent Chemical Group, R&D Division, Santoku Corp."},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Usui, Hiroyuki"},{"creatorName":"Usui, Hiroyuki","creatorNameLang":"en"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Nomura, Masahito"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nishino, Hiroki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kusatusu, Masatoshi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Murota, Tadatoshi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sakaguchi, Hiroki"},{"creatorName":"Sakaguchi, Hiroki","creatorNameLang":"en"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Nomura, Masahito","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nishino, Hiroki","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kusatusu, Masatoshi","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Murota, Tadatoshi","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-12-10"}],"displaytype":"detail","filename":"ml130_61.pdf","filesize":[{"value":"368.2 kB"}],"format":"application/pdf","licensefree":"Copyright © 2014 Elsevier B.V. All rights reserved. This manuscript version is made available under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ml130_61.pdf","url":"https://repository.lib.tottori-u.ac.jp/record/7296/files/ml130_61.pdf"},"version_id":"6b811c69-ea9d-4629-ad3b-87c84f3ce90f"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Rare-earth metal silicide","subitem_subject_scheme":"Other"},{"subitem_subject":"Si-based composite anode","subitem_subject_scheme":"Other"},{"subitem_subject":"Gadolinium silicide","subitem_subject_scheme":"Other"},{"subitem_subject":"Thick-film electrode","subitem_subject_scheme":"Other"},{"subitem_subject":"Gas-deposition method","subitem_subject_scheme":"Other"},{"subitem_subject":"Li-ion battery","subitem_subject_scheme":"Other"},{"subitem_subject":"Rare-earth metal silicide","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Si-based composite anode","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Gadolinium silicide","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Thick-film electrode","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Gas-deposition method","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Li-ion battery","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article"}]},"item_title":"Gadolinium silicide/silicon composite with excellent high-rate performance as lithium-ion battery anode","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Gadolinium silicide/silicon composite with excellent high-rate performance as lithium-ion battery anode","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"10","path":["12","10"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-06-22"},"publish_date":"2018-06-22","publish_status":"0","recid":"7296","relation_version_is_last":true,"title":["Gadolinium silicide/silicon composite with excellent high-rate performance as lithium-ion battery anode"],"weko_creator_id":"10","weko_shared_id":-1},"updated":"2023-09-29T00:44:15.488087+00:00"}