{"created":"2023-08-02T03:58:09.546747+00:00","id":7310,"links":{},"metadata":{"_buckets":{"deposit":"4adac2b1-c4ea-4703-ac99-f57956b78809"},"_deposit":{"created_by":10,"id":"7310","owners":[10],"pid":{"revision_id":0,"type":"depid","value":"7310"},"status":"published"},"_oai":{"id":"oai:repository.lib.tottori-u.ac.jp:00007310","sets":["1:10","2:12"]},"author_link":["4778","27155","27156","1334","27157","27158"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"117","bibliographicPageStart":"110","bibliographicVolumeNumber":"435","bibliographic_titles":[{"bibliographic_title":"Molecular catalysis"},{"bibliographic_title":"Molecular catalysis","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Impregnation of various heteroelements on the ZSM-5 zeolite was applied to improvement of the catalytic activity in toluene disproportionation. Nickel loaded on ZSM-5 (Ni/ZSM-5) exhibited higher catalytic activity (toluene conversion) and lower benzene / xylene ratio (closer to the stoichiometry, meaning low rate of side reaction) than H-ZSM-5 zeolite. The Ni/ZSM-5 with Ni/Al = 0.6 showed the maximum in catalytic activity, and excess Ni loading caused decrease in the conversion and increase in the benzene / xylene ratio due to decrease of acid amount and acceleration of dealkylation, respectively. The detailed analysis of acidic property by means of ammonia IRMS-TPD method showed that the Ni loading generated Lewis acid sites on the zeolite. The synergy of Brønsted and Lewis acid sites, ascribed to Si-OH-Al and Ni species, respectively, is suggested to give the high activity of desired reaction.","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier"}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.mcat.2017.03.029","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_16":{"attribute_name":"情報源","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"This work was published by Elsevier: Suganuma, S., Nakamura, K., Okuda, A., Katada, N., Enhancement of Catalytic Activity for Toluene Disproportionation by Loading Lewis Acidic Nickel Species on ZSM-5 Zeolite, Molecular catalysis. 2017, 435, 110-117. doi:"}]}]},"item_10001_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://www.sciencedirect.com/science/article/pii/S2468823117301918"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.sciencedirect.com/science/article/pii/S2468823117301918","subitem_relation_type_select":"URI"}}]},"item_10001_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © 2017 Elsevier B.V. All rights reserved. This manuscript version is made available   under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/"}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"24688231","subitem_source_identifier_type":"ISSN"}]},"item_10001_text_32":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"Center for Research on Green Sustainable Chemistry, Graduate School of Engineering, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University"},{"subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University"}]},"item_10001_text_33":{"attribute_name":"著者所属（英）","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Center for Research on Green Sustainable Chemistry, Graduate School of Engineering, Tottori University"},{"subitem_text_language":"en","subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University"},{"subitem_text_language":"en","subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University"},{"subitem_text_language":"en","subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Suganuma, Satoshi"},{"creatorName":"Suganuma, Satoshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"4778","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"90731753","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=90731753"},{"nameIdentifier":"100001271","nameIdentifierScheme":"研究者総覧鳥取大学","nameIdentifierURI":"http://researchers.adm.tottori-u.ac.jp/html/100001271_ja.html"}]},{"creatorNames":[{"creatorName":"Nakamura, Koshiro"}],"nameIdentifiers":[{"nameIdentifier":"27155","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Okuda, Akihito"}],"nameIdentifiers":[{"nameIdentifier":"27156","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Katada, Naonobu"},{"creatorName":"Katada, Naonobu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"1334","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"00243379","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=00243379"},{"nameIdentifier":"100000492","nameIdentifierScheme":"研究者総覧鳥取大学","nameIdentifierURI":"http://researchers.adm.tottori-u.ac.jp/html/100000492_ja.html"}]},{"creatorNames":[{"creatorName":"Nakamura, Koshiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"27157","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Okuda, Akihito","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"27158","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-03-17"}],"displaytype":"detail","filename":"mc435_110.pdf","filesize":[{"value":"789.1 kB"}],"format":"application/pdf","licensefree":"Copyright © 2017 Elsevier B.V. All rights reserved. This manuscript version is made available   under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"mc435_110.pdf","url":"https://repository.lib.tottori-u.ac.jp/record/7310/files/mc435_110.pdf"},"version_id":"decc7f6c-f444-412d-94fe-c641a4e56a76"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"ZSM-5","subitem_subject_scheme":"Other"},{"subitem_subject":"Ni loading","subitem_subject_scheme":"Other"},{"subitem_subject":"toluene disproportionation","subitem_subject_scheme":"Other"},{"subitem_subject":"acidic property","subitem_subject_scheme":"Other"},{"subitem_subject":"synergy effect","subitem_subject_scheme":"Other"},{"subitem_subject":"ZSM-5","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Ni loading","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"toluene disproportionation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"acidic property","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"synergy effect","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Enhancement of Catalytic Activity for Toluene Disproportionation by Loading Lewis Acidic Nickel Species on ZSM-5 Zeolite","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Enhancement of Catalytic Activity for Toluene Disproportionation by Loading Lewis Acidic Nickel Species on ZSM-5 Zeolite","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"10","path":["12","10"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-12-14"},"publish_date":"2018-12-14","publish_status":"0","recid":"7310","relation_version_is_last":true,"title":["Enhancement of Catalytic Activity for Toluene Disproportionation by Loading Lewis Acidic Nickel Species on ZSM-5 Zeolite"],"weko_creator_id":"10","weko_shared_id":-1},"updated":"2023-11-22T01:50:37.907255+00:00"}