{"created":"2023-08-02T03:58:09.593578+00:00","id":7311,"links":{},"metadata":{"_buckets":{"deposit":"7c189eb3-b958-411f-b505-0de5ee6606c6"},"_deposit":{"created_by":10,"id":"7311","owners":[10],"pid":{"revision_id":0,"type":"depid","value":"7311"},"status":"published"},"_oai":{"id":"oai:repository.lib.tottori-u.ac.jp:00007311","sets":["1:10","2:12"]},"author_link":["4778","27159","27160","4855","1334","27161","27162"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-04-30","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"92","bibliographicPageStart":"85","bibliographicVolumeNumber":"449","bibliographic_titles":[{"bibliographic_title":"Molecular Catalysis"},{"bibliographic_title":"Molecular Catalysis","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Glycerol is a promising renewable feedstock for the manufacture of C3 derivatives. We investigated the one-pass oxidehydrarion of glycerol through the dehydration of glycerol into acrolein, followed by the oxidation of acrolein. A novel bifunctional catalyst for this reaction was prepared by loading the Keggin-type molybdovanadophosphoric acid H3+xPVxMo12-xO40 (x = 0–3) on ZSM-5 (MFI) zeolite (Si/Al = 45) exhibiting both dehydration and oxidation activity. H5PV2Mo10O40 and H6PV3Mo9O40 were stable and dispersed on ZSM-5 zeolite, and the acidic property of the ZSM-5 zeolite was retained. The oxidehydration of glycerol was catalyzed by H5PV2Mo10O40 loaded on the ZSM-5 zeolite with high selectivity of acrylic acid. In-situ IR analysis suggests that acrolein molecules adsorbed on H5PV2Mo10O40/ZSM-5 were converted into acrylic acid due to the inhibition of side-reactions such as polymerization and auto-condensation, which induced coke formation, compared with the other Mo and V-based oxides loaded on ZSM-5 zeolite.","subitem_description_type":"Other"}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.mcat.2018.02.015","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_16":{"attribute_name":"情報源","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"Suganuma, Satoshi. Hisazumi, Takuya. Taruya, Kohtaro. et al. Keggin-type molybdovanadophosphoric acids loaded on ZSM-5 zeolite as a bifunctional catalyst for oxidehydration of glycerol. Molecular Catalysis. 449. 85-92. 2018-04-30."}]}]},"item_10001_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://www.sciencedirect.com/science/article/pii/S2468823118300701"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.sciencedirect.com/science/article/pii/S2468823118300701","subitem_relation_type_select":"URI"}}]},"item_10001_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2018 Elsevier B.V. All rights reserved."}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"24688231","subitem_source_identifier_type":"ISSN"}]},"item_10001_text_33":{"attribute_name":"著者所属（英）","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Center for Research on Green Sustainable Chemistry, Graduate School of Engineering"},{"subitem_text_language":"en","subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University"},{"subitem_text_language":"en","subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University"},{"subitem_text_language":"en","subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University"},{"subitem_text_language":"en","subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"菅沼, 学史"},{"creatorName":"スガヌマ, サトシ","creatorNameLang":"ja-Kana"},{"creatorName":"Suganuma, Satoshi","creatorNameLang":"en"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"ヒサズミ, タクヤ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"タルヤ, コウタロウ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"辻, 悦司"},{"creatorName":"ツジ, エツシ","creatorNameLang":"ja-Kana"},{"creatorName":"Tsuji, Etsushi","creatorNameLang":"en"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"片田, 直伸"},{"creatorName":"カタダ, ナオノブ","creatorNameLang":"ja-Kana"},{"creatorName":"Katada, Naonobu","creatorNameLang":"en"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Hisazumi, Takuya","creatorNameLang":"en"},{"creatorName":"ヒサズミ, タクヤ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Taruya, Kohtaro","creatorNameLang":"en"},{"creatorName":"タルヤ, コウタロウ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-03-17"}],"displaytype":"detail","filename":"mc449_85.pdf","filesize":[{"value":"984.7 kB"}],"format":"application/pdf","licensefree":"© 2018 Elsevier B.V. All rights reserved.","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"mc449_85.pdf","url":"https://repository.lib.tottori-u.ac.jp/record/7311/files/mc449_85.pdf"},"version_id":"e5093781-54ab-43df-abee-46f4dbe975b5"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Glycerol","subitem_subject_scheme":"Other"},{"subitem_subject":"Oxidehydration","subitem_subject_scheme":"Other"},{"subitem_subject":"Acrylic acid","subitem_subject_scheme":"Other"},{"subitem_subject":"ZSM-5 zeolite","subitem_subject_scheme":"Other"},{"subitem_subject":"Keggin-type heteropoly acid","subitem_subject_scheme":"Other"},{"subitem_subject":"Glycerol","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Oxidehydration","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Acrylic acid","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"ZSM-5 zeolite","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Keggin-type heteropoly acid","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article"}]},"item_title":"Keggin-type molybdovanadophosphoric acids loaded on ZSM-5 zeolite as a bifunctional catalyst for oxidehydration of glycerol","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Keggin-type molybdovanadophosphoric acids loaded on ZSM-5 zeolite as a bifunctional catalyst for oxidehydration of glycerol","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"10","path":["12","10"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-07-29"},"publish_date":"2020-07-29","publish_status":"0","recid":"7311","relation_version_is_last":true,"title":["Keggin-type molybdovanadophosphoric acids loaded on ZSM-5 zeolite as a bifunctional catalyst for oxidehydration of glycerol"],"weko_creator_id":"10","weko_shared_id":-1},"updated":"2023-11-22T01:50:43.803061+00:00"}