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Schmidtś "Doppelbindungsregel” のπ電子理論による解釈
https://repository.lib.tottori-u.ac.jp/records/1498
https://repository.lib.tottori-u.ac.jp/records/14981c8d8afa-aa80-4f42-8aad-f63c0c8f8106
| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2018-12-26 | |||||
| タイトル | ||||||
| タイトル | Schmidtś "Doppelbindungsregel” のπ電子理論による解釈 | |||||
| 言語 | ja | |||||
| タイトル | ||||||
| タイトル | The Interpretation based on the π-electron Theory for Suchmidtś "Doppelbindungsregel" | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | jpn | |||||
| 資源タイプ | ||||||
| 資源タイプ | departmental bulletin paper | |||||
| アクセス権 | ||||||
| アクセス権 | metadata only access | |||||
| タイトル（ヨミ） | ||||||
| その他のタイトル | Schmidtś "Doppelbindungsregel” ノ π デンシ リロン ニヨル カイシャク | |||||
| 言語 | ja-Kana | |||||
| 著者 |
遠藤, 雄吉
× 遠藤, 雄吉× ENDO, yukichi |
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| 著者所属 | ||||||
| 値 | 化学教室 | |||||
| 抄録 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | In order to clarify the essential meaning of Schmidt's "Doppelbindungsregel", the author made some calculation with cycrohexene as an example. Therein molecular orbital method was used the molecular symmetry of cycrohexene was taken into account to solve easily the seculiar equation for molecular orbitals, Wheland's approximation was applied with overlap integrals instead of Hückel's, and thus π-electron bond orders were evaluated foe excited states of this molecule. Therefrom the aforementioned "Regel" was explained with the following results : 1) Cycrohexene is regarded as the system of ten π-electrons on the basis of the hyper-conjugational effect. Four electrons of them in pair occupy non-bonding orbitals and the other six occupy bonding orbititals. States of these six electrons closely resemble those of benzene. 2) Rhythm of variation is clearly found from bond to bond in the π-electron bond orders of certain excited states and accordingly in the strength of c-c bonds, so that this molecular is supposed to be readily broken into parts at bonds having the smallest value of their bond orders. | |||||
| 書誌情報 |
ja : 鳥取大学教育学部研究報告. 自然科学 en : The Journal of the Faculty of Education, Tottori University. Natural science 巻 17, p. 32-47, 発行日 1966-12-20 |
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| 出版者 | ||||||
| 出版者 | 鳥取大学教育学部 | |||||
| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 03715965 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AN00174585 | |||||
| 権利 | ||||||
| 権利情報 | 注があるものを除き、この著作物は日本国著作権法により保護されています。 / This work is protected under Japanese Copyright Law unless otherwise noted. | |||||
| 情報源 | ||||||
| 関連名称 | 鳥取大学教育学部研究報告. 自然科学. 1966,17, 32-47 | |||||
