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Enhanced Performance of Sn4P3 Electrode Cycled in Ionic Liquid Electrolyte at Intermediate Temperature as Na‐Ion Battery Anode
https://repository.lib.tottori-u.ac.jp/records/7150
https://repository.lib.tottori-u.ac.jp/records/7150f504392b-a9a6-4fa1-b91f-da42f37b8c28
名前 / ファイル | ライセンス | アクション |
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cs3(29)_8462.pdf (1.0 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2019-07-09 | |||||
タイトル | ||||||
タイトル | Enhanced Performance of Sn4P3 Electrode Cycled in Ionic Liquid Electrolyte at Intermediate Temperature as Na‐Ion Battery Anode | |||||
言語 | en | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | Na-ion battery | |||||
キーワード | ||||||
主題 | Anode materials | |||||
キーワード | ||||||
主題 | Tin phosphide (Sn4P3) | |||||
キーワード | ||||||
主題 | Ionic liquid electrolyte | |||||
キーワード | ||||||
主題 | Intermediate temperature | |||||
キーワード | ||||||
言語 | en | |||||
主題 | Na-ion battery | |||||
キーワード | ||||||
言語 | en | |||||
主題 | Anode materials | |||||
キーワード | ||||||
言語 | en | |||||
主題 | Tin phosphide (Sn4P3) | |||||
キーワード | ||||||
言語 | en | |||||
主題 | Ionic liquid electrolyte | |||||
キーワード | ||||||
言語 | en | |||||
主題 | Intermediate temperature | |||||
資源タイプ | ||||||
資源タイプ | journal article | |||||
著者 |
Usui, Hiroyuki
× Usui, Hiroyuki× Domi, Yasuhiro× Nishida, Haruka× Yamaguchi, Kazuki× Yamagami, Ryota× Sakaguchi, Hiroki |
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著者所属(英) | ||||||
言語 | en | |||||
値 | Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University / Center for Research on Green Sustainable Chemistry, Tottori University | |||||
著者所属(英) | ||||||
言語 | en | |||||
値 | Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University / Center for Research on Green Sustainable Chemistry, Tottori University | |||||
著者所属(英) | ||||||
言語 | en | |||||
値 | Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University / Center for Research on Green Sustainable Chemistry, Tottori University | |||||
著者所属(英) | ||||||
言語 | en | |||||
値 | Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University / Center for Research on Green Sustainable Chemistry, Tottori University | |||||
著者所属(英) | ||||||
言語 | en | |||||
値 | Course of Chemistry and Biotechnology, Department of Engineering, Graduate School of Sustainability Science, Tottori University / Center for Research on Green Sustainable Chemistry, Tottori University | |||||
著者所属(英) | ||||||
言語 | en | |||||
値 | Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University / Center for Research on Green Sustainable Chemistry, Tottori University | |||||
抄録 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Charge-discharge performances of Sn4P3 anodes for Na‐ion battery were evaluated in an ionic liquid electrolyte using N‐methyl‐N‐propylpyrrolidinium bis(fluorosulfonyl)amide at intermediate temperatures of 60 and 90 oC. At these temperatures, the anode showed extra capacities based on the full sodiation of Sn in a potential range below 0.2 V vs. Na+/Na because its slow kinetics was improved by elevating operation temperature. Under the current density of 0.1 A g-1 (0.08 C), the Sn4P3 anode at 60 oC exhibited a large capacity of 750 mA h g-1 at the 120th cycle and high Coulombic efficiencies above 99% after the 5th cycle. On the other hand, the efficiency degraded at 90 oC by the electrolyte decomposition. At 60 oC, the anode attained an excellent rate performance with capacity of 250 mA h g-1 even at 3 A g-1 (2.65 C). These results demonstrated the promising operation at intermediate temperature at around 60 oC for Sn4P3 anode in ionic liquid electrolyte. | |||||
書誌情報 |
ChemistrySelect en : ChemistrySelect 巻 3, 号 29, p. 8462-8467, 発行日 2018-08-01 |
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出版者 | ||||||
出版者 | Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 23656549 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1002/slct.201801517 | |||||
権利 | ||||||
権利情報 | © 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim | |||||
情報源 | ||||||
関連名称 | This research was published by Wiley.: USUI, Hiroyuki, et al. Enhanced Performance of Sn4P3 Electrode Cycled in Ionic Liquid Electrolyte at Intermediate Temperature as Na‐Ion Battery Anode. ChemistrySelect, 2018, 3.29: 8462-8467. https://doi.org/10.1002/s | |||||
関連サイト | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://onlinelibrary.wiley.com/doi/abs/10.1002/slct.201801517 | |||||
関連名称 | https://onlinelibrary.wiley.com/doi/abs/10.1002/slct.201801517 | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa |