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Novel Composite Thick-Film Electrodes Consisted of Zinc Oxide and Silicon for Lithium-Ion Battery Anode
https://repository.lib.tottori-u.ac.jp/records/7218
https://repository.lib.tottori-u.ac.jp/records/72189517e523-ae38-487f-8df5-50becd56b79c
名前 / ファイル | ライセンス | アクション |
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ijes7(5)_4322.pdf (1.1 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2018-06-22 | |||||
タイトル | ||||||
タイトル | Novel Composite Thick-Film Electrodes Consisted of Zinc Oxide and Silicon for Lithium-Ion Battery Anode | |||||
言語 | en | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | Zinc oxide | |||||
キーワード | ||||||
主題 | Silicon | |||||
キーワード | ||||||
主題 | Thick-film electrode | |||||
キーワード | ||||||
主題 | Conversion reaction | |||||
キーワード | ||||||
主題 | Gas-deposition method | |||||
キーワード | ||||||
主題 | Li-ion battery | |||||
キーワード | ||||||
言語 | en | |||||
主題 | Zinc oxide | |||||
キーワード | ||||||
言語 | en | |||||
主題 | Silicon | |||||
キーワード | ||||||
言語 | en | |||||
主題 | Thick-film electrode | |||||
キーワード | ||||||
言語 | en | |||||
主題 | Conversion reaction | |||||
キーワード | ||||||
言語 | en | |||||
主題 | Gas-deposition method | |||||
キーワード | ||||||
言語 | en | |||||
主題 | Li-ion battery | |||||
資源タイプ | ||||||
資源タイプ | journal article | |||||
著者 |
Usui, Hiroyuki
× Usui, Hiroyuki× Kono, Takamasa× Sakaguchi, Hiroki× Kono, Takamasa |
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著者所属 | ||||||
値 | Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University | |||||
著者所属 | ||||||
値 | Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University | |||||
著者所属 | ||||||
値 | Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University | |||||
抄録 | ||||||
内容記述タイプ | Other | |||||
内容記述 | As a novel anode for Li-ion battery, ZnO/Si composite thick-film electrodes with various ratios of ZnO:Si were prepared by a gas-deposition method using a commercial Si powder and a radial-shaped ZnO powder synthesized by a precipitation method. We investigated the effect of the ZnO amount and the radial morphology on the anode performance, comparing with charge–discharge properties of a ZnO electrode without Si. The ZnO electrode showed a stable cyclability and a moderate discharge capacity of 160–220 mA h g-1 after the 20th cycle. The composite electrode of ZnO/Si with a ratio of 89/11 wt.% exhibited a good cycle stability after the 20th cycle and large discharge capacities exceeding the theoretical capacity of graphite until the 370th cycle. In contrast, a composite electrode containing of crushed ZnO showed a flat surface and poor performance. These results revealed that microstructure of the radial-shaped ZnO is very favorable for improving efficiencies of electrode reactions due to its high surface area, and is effective in accommodating the stresses induced by Li-insertion and Li-extraction in/from Si. | |||||
書誌情報 |
International Journal of Electrochemical Science en : International Journal of Electrochemical Science 巻 7, 号 5, p. 4322-4334, 発行日 2012-05-01 |
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出版者 | ||||||
出版者 | ESG | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 14523981 | |||||
権利 | ||||||
権利情報 | © 2012 by ESG (www.electrochemsci.org) | |||||
情報源 | ||||||
関連名称 | International Journal of Electrochemical Science. 2012, 7(5), 4322-4334 | |||||
関連サイト | ||||||
識別子タイプ | URI | |||||
関連識別子 | http://www.electrochemsci.org/papers/vol7/7054322.pdf | |||||
関連名称 | http://www.electrochemsci.org/papers/vol7/7054322.pdf | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |