{"_buckets": {"deposit": "8594272a-fa10-4adb-9b4e-e1e79924458b"}, "_deposit": {"created_by": 1, "id": "3477", "owners": [1], "pid": {"revision_id": 0, "type": "depid", "value": "3477"}, "status": "published"}, "_oai": {"id": "oai:repository.lib.tottori-u.ac.jp:00003477", "sets": ["10", "14", "708"]}, "author_link": ["33876", "33877", "4287"], "item_3_alternative_title_31": {"attribute_name": "タイトル（ヨミ）", "attribute_value_mlt": [{"subitem_alternative_title": "アゾキシベンゼン　ノ　ハンノウセイ　ニカンスル　ケンキュウ　（ダイ１ポウ） : 2,2\u0027-ジメチルアゾキシベンゼン　ノ　ワラッハ　テンイ"}]}, "item_3_biblio_info_7": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "1970-12-20", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1", "bibliographicPageEnd": "49", "bibliographicPageStart": "45", "bibliographicVolumeNumber": "1", "bibliographic_titles": [{"bibliographic_title": "鳥取大学工学部研究報告"}, {"bibliographic_title": "Reports of the Faculty of Engineering, Tottori University", "bibliographic_titleLang": "en"}]}]}, "item_3_checkbox_26": {"attribute_name": "部局名", "attribute_value_mlt": [{"subitem_checkbox_item": ["kou-gakubu"]}]}, "item_3_description_5": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "　In this paper we authors studied on Wallach rearrangement reaction of 2,2\u0027-dimethyl azoxybenzene (DMAB) using sulfuric acid, chlorosulfonic acid and some other weak acids as catalysts, and obtained the following results ; (1) We could obtain 4-hydroxy-2,2\u0027-dimethyl azobenzene as a rearrangement product from DMAB in 80% sulfuric acid, under the reaction temperature 80℃ and time 30 minutes. The yield of 64% obtained in this experiment was better than that of 31% at which Gore et al had obtained the product.  (2) In case where chlorosulfonic acid was used in the rearrangement, It is a contradictory results against Wallach rearrangement by ordinary acid catalysts. The yield of o-isomer in the reaction products was higher than that of p-isomer in rearrangement. (3) We also tried Wallach rearrangement by weak acids for the first taime, and obtained p-isomer at yield of max. 38.8% with trichloroacetic acid in acetic anhydride.", "subitem_description_type": "Abstract"}]}, "item_3_publisher_8": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "鳥取大学工学部"}]}, "item_3_relation_16": {"attribute_name": "情報源", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "鳥取大学工学部研究報告. 1970, 1(1), 45-49"}]}]}, "item_3_rights_15": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "注があるものを除き、この著作物は日本国著作権法により保護されています。 / This work is protected under Japanese Copyright Law unless otherwise noted."}]}, "item_3_source_id_11": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AN00174610", "subitem_source_identifier_type": "NCID"}]}, "item_3_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "03858596", "subitem_source_identifier_type": "ISSN"}]}, "item_3_text_24": {"attribute_name": "EARMAS ID", "attribute_value_mlt": [{"subitem_text_value": "2099"}]}, "item_3_text_28": {"attribute_name": "最新掲載誌名", "attribute_value_mlt": [{"subitem_text_value": "rgsfe;鳥取大学大学院工学研究科／工学部研究報告;Reports of the Faculty of Engineering, Tottori University"}]}, "item_3_text_32": {"attribute_name": "著者所属", "attribute_value_mlt": [{"subitem_text_value": "鳥取大学工学部工業化学科"}, {"subitem_text_value": "永和化成工業K.K."}]}, "item_3_version_type_20": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "山本, 二郎"}, {"creatorName": "ヤマモト, ジロウ", "creatorNameLang": "ja-Kana"}, {"creatorName": "Yamamoto, Jiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "4287", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "30032022", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=30032022"}]}, {"creatorNames": [{"creatorName": "佐藤, 憲章"}, {"creatorName": "サトウ, ノリアキ", "creatorNameLang": "ja-Kana"}], "nameIdentifiers": [{"nameIdentifier": "33876", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sato, Noriaki", "creatorNameLang": "en"}, {"creatorName": "サトウ, ノリアキ", "creatorNameLang": "ja-Kana"}], "nameIdentifiers": [{"nameIdentifier": "33877", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2009-12-09"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "rfetu1(1)_45(1).pdf", "filesize": [{"value": "329.7 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensefree": "注があるものを除き、この著作物は日本国著作権法により保護されています。 / This work is protected under Japanese Copyright Law unless otherwise noted.", "licensetype": "license_free", "mimetype": "application/pdf", "size": 329700.0, "url": {"label": "rfetu1(1)_45(1).pdf", "url": "https://repository.lib.tottori-u.ac.jp/record/3477/files/rfetu1(1)_45(1).pdf"}, "version_id": "bf45e905-1426-488d-a59b-da9514f1838c"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "アゾキシベンゼンの反応性に関する研究（第1報） : 2,2\u0027-ジメチルアゾキシベンゼンのワラッハ転位", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "アゾキシベンゼンの反応性に関する研究（第1報） : 2,2\u0027-ジメチルアゾキシベンゼンのワラッハ転位"}, {"subitem_title": "Reactivities of azoxybenzenes (I) : Wallach rearrangement of 2,2\u0027-dimetlyl azoxybenzene", "subitem_title_language": "en"}]}, "item_type_id": "3", "owner": "1", "path": ["10", "14", "708"], "permalink_uri": "https://repository.lib.tottori-u.ac.jp/records/3477", "pubdate": {"attribute_name": "公開日", "attribute_value": "2018-06-22"}, "publish_date": "2018-06-22", "publish_status": "0", "recid": "3477", "relation": {}, "relation_version_is_last": true, "title": ["アゾキシベンゼンの反応性に関する研究（第1報） : 2,2\u0027-ジメチルアゾキシベンゼンのワラッハ転位"], "weko_shared_id": -1}