| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2020-07-29 |
| タイトル |
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|
タイトル |
Compensation between activation entropy and enthalpy in reactions of aromatic hydrocarbons catalyzed by solid acids |
|
言語 |
en |
| 言語 |
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|
言語 |
eng |
| 資源タイプ |
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|
資源タイプ |
journal article |
| 著者 |
ナカムラ, コウシロウ
ミズタ, リョウ
菅沼, 学史
辻, 悦司
片田, 直伸
Nakamura, Koshiro
Mizuta, Ryo
|
| 著者所属（英） |
|
|
言語 |
en |
|
値 |
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University |
| 著者所属（英） |
|
|
言語 |
en |
|
値 |
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University |
| 著者所属（英） |
|
|
言語 |
en |
|
値 |
Center for Research on Green Sustainable Chemistry, Faculty of Engineering, Tottori University |
| 著者所属（英） |
|
|
言語 |
en |
|
値 |
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University |
| 著者所属（英） |
|
|
言語 |
en |
|
値 |
Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University |
| 抄録 |
|
|
内容記述タイプ |
Other |
|
内容記述 |
Reaction rates of toluene disproportionation (A) and cumene cracking (B) normalized by the number of Brønsted acid sites were analyzed on aluminosilicates. The activation entropy showed linear and compensatory relationship against the activation enthalpy. The slope of entropy-enthalpy plot was in the order of (B)>(A)>small alkane cracking, whereas the intercept on the horizontal axis was in the order of propane and isobutane cracking>linear C4–8 alkanes and iso-pentane cracking>(A)>(B). The former is consistent with the bulkiness of reactant, while the latter is consistent with intrinsic difficulty of formation of intermediate cations. |
| 書誌情報 |
Catalysis Communications
en : Catalysis Communications
巻 102,
p. 103-107,
発行日 2017-12-31
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| ISSN |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
15667367 |
| 書誌レコードID |
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収録物識別子タイプ |
NCID |
|
収録物識別子 |
AA1180723X |
| DOI |
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|
関連タイプ |
isVersionOf |
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|
識別子タイプ |
DOI |
|
|
関連識別子 |
10.1016/j.catcom.2017.08.033 |
| 権利 |
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|
権利情報 |
© 2017 Elsevier B.V. All rights reserved. |
| 情報源 |
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関連名称 |
Nakamura, Koshiro. Mizuta, Ryo. Suganuma, Satoshi. et al. Compensation between activation entropy and enthalpy in reactions of aromatic hydrocarbons catalyzed by solid acids. Catalysis Communications. 102. 103-107. 2017-12-31. |
| 関連サイト |
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|
識別子タイプ |
URI |
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|
関連識別子 |
https://www.sciencedirect.com/science/article/pii/S1566736717303734 |
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|
関連名称 |
https://www.sciencedirect.com/science/article/pii/S1566736717303734 |
| 著者版フラグ |
|
|
出版タイプ |
AM |
cc102_103.pdf (447.5 kB)
