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Lithiation and Delithiation Reactions of Binary Silicide Electrodes in an Ionic Liquid Electrolyte as Novel Anodes for Lithium‐Ion Batteries

https://repository.lib.tottori-u.ac.jp/records/7134
https://repository.lib.tottori-u.ac.jp/records/7134
efc0c4b4-ee90-4c34-a1f1-9f27fd8522e3
名前 / ファイル ライセンス アクション
cec6(2)_581.pdf cec6(2)_581.pdf (4.0 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2019-07-09
タイトル
タイトル Lithiation and Delithiation Reactions of Binary Silicide Electrodes in an Ionic Liquid Electrolyte as Novel Anodes for Lithium‐Ion Batteries
言語 en
言語
言語 eng
キーワード
主題 lithium-ion batteries
キーワード
主題 silicide
キーワード
主題 ionic liquid electrolyte
キーワード
主題 gas deposition
キーワード
主題 soft X-ray emission spectroscopy
キーワード
言語 en
主題 lithium-ion batteries
キーワード
言語 en
主題 silicide
キーワード
言語 en
主題 ionic liquid electrolyte
キーワード
言語 en
主題 gas deposition
キーワード
言語 en
主題 soft X-ray emission spectroscopy
資源タイプ
資源タイプ journal article
著者 Domi, Yasuhiro

× Domi, Yasuhiro

WEKO 254
e-Rad 50576717
研究者総覧鳥取大学 100001303

en Domi, Yasuhiro

Search repository
Usui, Hiroyuki

× Usui, Hiroyuki

WEKO 4098
e-Rad 60423240
研究者総覧鳥取大学 100000473

en Usui, Hiroyuki

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Takaishi, Rena

× Takaishi, Rena

WEKO 26419

en Takaishi, Rena

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Sakaguchi, Hiroki

× Sakaguchi, Hiroki

WEKO 3101
e-Rad 00202086
研究者総覧鳥取大学 100000517

en Sakaguchi, Hiroki

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著者所属(英)
言語 en
値 Department of Chemistry and Biotechnology, Graduate School of Enginnering, Tottori University / Center for Research on Green Sustainable Chemistry, Tottori University / Global Research Center for Environment and Energy based on Nanomaterials Science, National Institute for Materials Science
著者所属(英)
言語 en
値 Department of Chemistry and Biotechnology, Graduate School of Enginnering, Tottori University / Center for Research on Green Sustainable Chemistry, Tottori University / Global Research Center for Environment and Energy based on Nanomaterials Science, National Institute for Materials Science
著者所属(英)
言語 en
値 Graduate School of Sustainability Science, Tottori University / Center for Research on Green Sustainable Chemistry, Tottori University / Global Research Center for Environment and Energy based on Nanomaterials Science, National Institute for Materials Science
著者所属(英)
言語 en
値 Department of Chemistry and Biotechnology, Graduate School of Enginnering, Tottori University / Center for Research on Green Sustainable Chemistry, Tottori University / Global Research Center for Environment and Energy based on Nanomaterials Science, National Institute for Materials Science
抄録
内容記述タイプ Other
内容記述 We investigated the lithiation and delithiation properties of pure binary silicide electrodes in an ionic liquid electrolyte as novel anodes for lithium‐ion batteries. Some electrodes maintain a high reversible capacity in the electrolyte, whereas they show a poor cycling performance in an organic electrolyte. The superior performance results from the high affinity for the transition metal that composes the silicide with Li. Based on reaction behavior analysis, the crystal structure of silicide is maintained during the cycling, and phase separation does not occur. The ionic liquid electrolyte suppresses the formation of cracks and exfoliation of the silicide layer from a substrate. In addition, a surface film formed on the silicide electrode through the reductive decomposition of the electrolyte has different components than that on a Si electrode, even in the same ionic liquid electrolyte. Soft X‐ray emission spectroscopy demonstrates that the pure silicide itself reacts with Li. The obtained results will provide significant insights into novel alloy‐based anode materials for lithium‐ion batteries.
書誌情報 ChemElectroChem
en : ChemElectroChem

巻 6, 号 2, p. 581-589, 発行日 2018-10-12
出版者
出版者 Wiley-VCH Verlag GmbH & Co. KGaA.
ISSN
収録物識別子タイプ ISSN
収録物識別子 21960216
DOI
関連タイプ isIdenticalTo
識別子タイプ DOI
関連識別子 10.1002/celc.201801088
権利
権利情報 © 2018 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is pr
情報源
関連名称 This research was published by Wiley: DOMI, Yasuhiro, et al. Lithiation and Delithiation Reactions of Binary Silicide Electrodes in an Ionic Liquid Electrolyte as Novel Anodes for Lithium‐Ion Batteries. ChemElectroChem, 2019, 6.2: 581-589. https://doi.org
関連サイト
識別子タイプ URI
関連識別子 https://onlinelibrary.wiley.com/doi/full/10.1002/celc.201801088
関連名称 https://onlinelibrary.wiley.com/doi/full/10.1002/celc.201801088
著者版フラグ
出版タイプ VoR
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