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Gadolinium silicide/silicon composite with excellent high-rate performance as lithium-ion battery anode
https://repository.lib.tottori-u.ac.jp/records/7296
https://repository.lib.tottori-u.ac.jp/records/72963f63cb0e-ec76-4afb-9896-d0564b473ce8
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
ml130_61.pdf (368.2 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2018-06-22 | |||||
| タイトル | ||||||
| タイトル | Gadolinium silicide/silicon composite with excellent high-rate performance as lithium-ion battery anode | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| キーワード | ||||||
| 主題 | Rare-earth metal silicide | |||||
| キーワード | ||||||
| 主題 | Si-based composite anode | |||||
| キーワード | ||||||
| 主題 | Gadolinium silicide | |||||
| キーワード | ||||||
| 主題 | Thick-film electrode | |||||
| キーワード | ||||||
| 主題 | Gas-deposition method | |||||
| キーワード | ||||||
| 主題 | Li-ion battery | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題 | Rare-earth metal silicide | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題 | Si-based composite anode | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題 | Gadolinium silicide | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題 | Thick-film electrode | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題 | Gas-deposition method | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題 | Li-ion battery | |||||
| 資源タイプ | ||||||
| 資源タイプ | journal article | |||||
| 著者 |
Usui, Hiroyuki
× Usui, Hiroyuki× Nomura, Masahito× Nishino, Hiroki× Kusatusu, Masatoshi× Murota, Tadatoshi× Sakaguchi, Hiroki× Nomura, Masahito× Nishino, Hiroki× Kusatusu, Masatoshi× Murota, Tadatoshi |
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| 著者所属 | ||||||
| 値 | Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University | |||||
| 著者所属 | ||||||
| 値 | Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University | |||||
| 著者所属 | ||||||
| 値 | Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University | |||||
| 著者所属 | ||||||
| 値 | Intelligent Chemical Group, R&D Division, Santoku Corp. | |||||
| 著者所属 | ||||||
| 値 | Intelligent Chemical Group, R&D Division, Santoku Corp. | |||||
| 著者所属 | ||||||
| 値 | Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University/Center for Research on Green Sustainable Chemistry, Tottori University | |||||
| 抄録 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | Novel composite materials consisted of elemental Si and rare-earth metal silicides, Sm–Si, Gd–Si, and Dy–Si, were synthesized and were evaluated for the first time as a high-performance anode material of Li-ion battery. Thick-film electrodes of the silicide/Si composites were prepared by an arc melting method and a successive gas-deposition method. Among them, the Gd–Si/Si composite electrode exhibited reversible Li-insertion/extraction reactions and the best cycling performance: the initial Coulombic efficiency was 80% and the discharge capacity at the 1000th cycle was 840 mA h g–1. In addition to this, the composite electrode delivered a superb high-rate performance with the capacity of 2100 mA h g–1 even at the high current rate of 12.0 A g–1 (4.8C). The remarkable performances demonstrated that the gadolinium silicide is favorable to significantly enhance anode properties of Si-based composite electrodes. | |||||
| 書誌情報 |
Materials letters en : Materials letters 巻 130, p. 61-64, 発行日 2014-09-01 |
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| 出版者 | ||||||
| 出版者 | Elsevier | |||||
| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 0167577X | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA11537623 | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1016/j.matlet.2014.05.065 | |||||
| 権利 | ||||||
| 権利情報 | Copyright © 2014 Elsevier B.V. All rights reserved. This manuscript version is made available under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/ | |||||
| 情報源 | ||||||
| 関連名称 | Materials letters. 2014, 130, 61-64 | |||||
| 関連サイト | ||||||
| 識別子タイプ | URI | |||||
| 関連識別子 | http://www.sciencedirect.com/science/article/pii/S0167577X14008453 | |||||
| 関連名称 | http://www.sciencedirect.com/science/article/pii/S0167577X14008453 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
